TOMS
Triglycerides
Of
Modified
Structure
Sandy forwarded to me your recent mail to him
concerning our TBK-BD fuel (these days called "TOMS", i.e. Triglycerides Of
Modified Structure). To see its potentials, I am attaching to your kind
attention some further material. Sweden being in the vanguard of promoting
renewables, you may be in a position to do this with respect to our fuel, to
the mutual benefits of all involved. Please remember: there is
bio-ethyl
acetate manufacture going on in Sweden (
SEKAB Biofuels & Chemicals AB is capable of producing entirely fossil-free
ethyl acetate
http://www.sekab.com/chemistry/ethyl-acetate ) , so our fuel could be 100% renewable
via using this reagent (as against fossil-derived methanol in the FAME
process).
Please indicate what volumes of TOMS sample
you want and to what address. We never used algal oil but mostly rapeseed
oil and sunflower oil feedstocks. However, it makes very little difference what
feedstock oil/fat one uses for the partial interesterification with (m)ethyl
acetate, as the differences in fatty acid compositions of various
triglycerides can be well offset via choosing the right reaction parameters,
to attain the desired product properties (mainly it is all about viscosity
and cold properties).
Please remember that ours is a most versatile
"designer fuel" in the sense, that varying the percentage of long --> short chain
exchanges on the glycerol backbone, you can get 5 cSt --> 30 cSt viscosity
fuels, i.e. both D2 and D4 petrodiesel replacers, heating oils, etc.
Good luck to you.
Tomorrow I will arrange for your 10-litre TOMS
sample, made last
spring -- but stored properly -- from rapeseed oil, with a viscosity
of 6 - 6.5 cSt at 40°C. This could well substitute/blended with D2
petrodiesel.
Of the "heavy grade" replacer (> 20 cSt) we only produced
some years back, during our trial batches, so no samples remain.
But
the "real thing" was to attain the 5 - 6 cSt viscosities of EU/US FAME
standards, that we managed to do at last.
So please go ahead with this novel fuel and try to get the bio-ethyl
acetate manufacturer involved, so that we can come forward with a 100%
renewable diesel replacer.
If you add to this one of the
Danish
Novozyme enzyme transesterification catalysts, then no catalyst
neutralization will be required in our process, only a simple
filtering of the immobilized enzyme.
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02/01/2012